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IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 57, NO. 3, MARCH 2010
943
Electric Vehicle Using a Combination of
Ultracapacitors and ZEBRA Battery
Juan Dixon,
Senior Member, IEEE,
Ian Nakashima, Eduardo F. Arcos, and Micah Ortúzar
Abstract—The
sodium–nickel chloride battery, commonly
known as ZEBRA, has been used for an experimental electric
vehicle (EV). These batteries are cheaper than Li-ion cells and
have a comparable specific energy (in watt–hours per kilogram),
but one important limitation is their poor specific power (in watts
per kilogram). The main objective of this paper is to demonstrate
experimentally that the combination of ZEBRA batteries and
ultracapacitors (UCAPs) can solve the lack of specific power,
allowing an excellent performance in both acceleration and regen-
erative braking in an EV. The UCAP system was connected to the
ZEBRA battery and to the traction inverter through a buck–boost-
type dc–dc converter, which manages the energy flow with the help
of DSP controllers. The vehicle uses a brushless dc motor with a
nominal power of 32 kW and a peak power of 53 kW. The control
system measures and stores the following parameters: battery
voltage, car speed to adjust the energy stored in the UCAPs, in-
stantaneous currents in both terminals (battery and UCAPs), and
present voltage of the UCAP. The increase in range with UCAPs
results in more than 16% in city tests, where the application of
this type of vehicle is being oriented. The results also show that
this alternative is cheaper than Li-ion powered electric cars.
Index Terms—Energy
management, energy storage, road vehi-
cle electric propulsion.
Fig. 1. Specific power of the most common secondary batteries for EVs.
I. I
NTRODUCTION
ODIUM–NICKEL chloride batteries (ZEBRA) are a good
choice for electric vehicles (EVs) [1], [2]. They are safe
and low cost and can endure more than 1000 cycles without
significant degradation [3]. Moreover, they can be discharged
almost to 100% of its total capacity without degradation in
its cycle life. Its specific energy (in watt–hours per kilo-
gram) is comparable with high-quality batteries, like Li-ion
(120 Wh/kg). However, specific power (in watts per kilogram)
of ZEBRA batteries is rather low when compared with other
batteries as shown in Fig. 1 [4].
For example, Li-ion batteries have almost three times more
specific power than ZEBRA (around 400 W/kg), but its price in
terms of dollars per kilowatt hour is around three times higher.
Manuscript received January 11, 2009; revised July 6, 2009. First published
July 28, 2009; current version published February 10, 2010. This work was
supported in part by Fondecyt Project 1070751 and in part by Millenium Project
P-04-048-F.
J. Dixon is with the Department of Electrical Engineering, Pontificia Univer-
sidad Católica de Chile, 6904411 Santiago, Chile (e-mail: jdixon@ing.puc.cl.).
I. Nakashima is with CGE Transmisión, 8340434 Santiago, Chile (e-mail:
inakashi@gmail.com).
E. F. Arcos is with Woodtech S.A., 7550130 Santiago, Chile (e-mail:
farcos@gmail.com).
M. Ortúzar is with CAM-Endesa, 8330287 Santiago, Chile (e-mail:
mortuzar@gmail.com).
Color versions of one or more of the figures in this paper are available online
at http://ieeexplore.ieee.org.
Digital Object Identifier 10.1109/TIE.2009.2027920
S
Today, it is quite difficult to get a Li-ion battery at an affordable
price. The cheapest Li-ion batteries available today in the mar-
ket are the small-cell-type 18650 (3.6 V, 2.4 Ah), from which
a battery car, using around 4000 units, can be implemented [5].
However, the lowest market price per unit, buying more than
1000 of these cells, is US$4.75 per unit [6], which means that
for 4000 units, the cost is US$19 000. This value does not
consider the large amount of electronic circuits for voltage
balancing, temperature control, and current balancing, which
may increase the total cost to more than US$40 000. Besides,
this battery pack will need the container, reinforcements, me-
chanical protections and time to construct, which will increase
the cost of the battery, probably to more than US$50 000.
The maker of electric cars, AC Propulsion Systems, sells the
“TZero” EV, made with 6800-cell-type 18650, at a cost of
US$220 000. They also sell the same EV with lead-acid bat-
teries at US$80 000 [7], [8]. This difference in price means
that this battery with 6800 cells, with all the electronic sup-
port for safe operation, costs more than US$140 000. Then,
for 4000 cells, the cost is higher than US$82 000 (around
US$2400/kWh). AC propulsion decided to make the car with
those small units because this solution demonstrated to be
cheaper than a large Li-ion module (which is not easily avail-
able today). Another example is the Chevrolet “Volt” from GM.
This hybrid plug-in EV (also defined as range-extended EV) is
going to be commercialized by the end of 2009. It uses a Li-
ion battery pack of 16 kWh and GM estimates that the battery
alone will cost around 20 000 (US$800/kWh). However, this is
a very unreal estimation because, at present, the price of Li-ion
batteries for EVs is more than US$2000/kWh [9]. The price of
“TZero,” from AC Propulsion Systems, is a good example of
cost of Li-ion batteries today. The experimental vehicle under
study uses a ZEBRA battery of 28.2 kWh with a cost on the
order of US$19 000 [10] (real cost in March 2009), which
includes auxiliary control circuits (US$680/kWh). The ZEBRA
0278-0046/$26.00 © 2010 IEEE
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944
IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 57, NO. 3, MARCH 2010
Fig. 2. ZEBRA-type Z36-371-ML3X-76.
Fig. 4.
UCAP bank in front of the vehicle.
Fig. 5. Block diagram of the power system to manage the energy flow into the
vehicle.
Fig. 3. EV prototype.
being used in the experimental EV comes from factory in only
one pack, easy to install, which weights only 245 kg. It stores
28 kWh of useful energy, which gives a specific energy of
115 Wh/kg (the specific energy of the battery used by the
Chevrolet “Volt” is only 90 Wh/kg).
Fig. 2 shows the ZEBRA battery (type Z36-371-ML3X-76)
that is being used in the experimental EV [2]. This EV is shown
in Fig. 3 and was implemented at the Department of Electrical
Engineering of the Pontificia Universidad Católica de Chile
[11]. The car is powered by a 53-kW brushless-dc traction
motor and has a gross weight of 1700 kg [12].
To solve the lack of power problem, an ultracapacitor
(UCAP) bank was installed [13]–[15]. This bank, with a total
capacity of 20 F and 300 Vdc, stores a practical amount
of 200 Wh of energy. However, with this small amount of
energy, but with the big amount of specific power (more than
1000 W/kg), the UCAP can easily deliver 40 kW of power
during 20 s (more than enough to solve the lack of power of the
ZEBRA during the acceleration). In a similar way, during
regenerative braking, the UCAPs can receive, in a short period
of time, a high amount of energy. This is quite important be-
cause sudden peaks of negative power can increase the ZEBRA
battery voltage dangerously [16]–[18]. The actual cost of the
UCAP bank installed on the vehicle is around US$9000. How-
ever, road tests have demonstrated that a small capacitor bank
(80 Wh), with a cost of US$3000, is adequate for the accelera-
tion and regenerative braking (the weight of this small bank is
around 30 kg with frame included). Fig. 4 shows one of the
packs of UCAPs installed in front of the vehicle. The com-
bination of ZEBRA (high amount of energy but low specific
power) with UCAPs (low amount of energy but high specific
power) allows making an electric car [19], with better range,
good acceleration, and full regenerative braking capability [20].
II. P
OWER
C
IRCUIT
Fig. 5 shows the block diagram of the power circuit used in
the EV to manage the energy flow between ZEBRA, UCAPs,
and the traction system [21]. The battery feeds the power
inverter, and when the battery voltage goes low, the UCAPs
inject energy to both ZEBRA and inverter through the dc–dc
converter. This process keeps the battery voltage at normal val-
ues and helps the EV during acceleration. During regenerative
braking, the UCAPs recover the energy to avoid overvoltages at
the battery terminals. The dc–dc converter is water cooled and
weighs only 15 kg. It was designed and implemented at the De-
partment of Electrical Engineering, and the cost of implemen-
tation was less than US$2000. Taking into account the prices of
ZEBRA (US$19 000), UCAPs (US$3000), and dc–dc converter
(US$2000), the total cost of this system is US$851/kWh, which
is far lower than Li-ion price (today around US$2000/kWh).
Special control algorithms keep the capacitor voltage at
the required level, according to particular driving conditions
(mainly speed, battery state of charge (SOC), and UCAP
voltage).
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DIXON
et al.:
ELECTRIC VEHICLE USING A COMBINATION OF ULTRACAPACITORS AND ZEBRA BATTERY
945
UCAPs is needed. In this way, all the energy recovered from
regenerative braking will go to the UCAPs. By contrast, if the
battery SOC is poor, the UCAP should keep an amount of
energy higher than under normal conditions. The charge curves
of the UCAP for those operating conditions are shown in Fig. 8.
These curves were estimated, taking in account the time needed
by the control to store the right amount of energy into the
UCAP. This control, using the same TMS320F241, was also
implemented using neural networks strategy [22], [23].
The SOC is estimated by time integration of the battery
current (positive or negative). The system also recognizes a
fully charged battery when its voltage goes up rapidly under
a regenerative braking condition.
IV. S
IMULATION
R
ESULTS
Fig. 9 shows a simulation of the ZEBRA battery at 80%
depth of discharge (DOD) during acceleration of the vehicle
from 40 to 60 km/h in 4 s. The UCAPs are not connected, and
it can be seen that the battery voltage is strongly affected by the
current variations. A serious problem arises when battery has
to supply more than 150 A, because, in this case, the voltage
at the ZEBRA terminals drops to values smaller than 250 Vdc.
Under these conditions, the control of the traction motor reset
the PWM signals of the inverter due to undervoltage operation,
and the current cannot go higher. The simulation shows, in
dot lines, the unreachable current when voltage goes below
250 V, because, in fact, the vehicle cannot work under these
conditions.
The deep variation of the ZEBRA voltage is due to the poor
specific power of this kind of battery. The only way to avoid
this problem without power assistance is to keep a very low
acceleration value.
Fig. 10 shows the ZEBRA battery at the same 80% DOD,
but with UCAPs, accelerating the vehicle from 40 to 60 km/h
in 4 s. In this case, the battery voltage is not seriously affected
by the current variations because UCAPs are injecting power to
the system to keep the ZEBRA current limited to 70 A. Under
this condition, the voltage cannot go lower than 320 Vdc unless
UCAPs become fully discharged. After acceleration comes to
an end, the control adjusts the UCAP voltage according to
car speed and battery SOC. During constant speed, the battery
voltage recovers its normal operating value (around 370 V,
depending on current released by the ZEBRA battery at that
speed). As was already mentioned, at higher speeds, UCAPs
are fully discharged (at factory limits). When a vehicle travels
at medium speeds, the UCAPs keep some charge to have energy
for future acceleration. Similarly, the UCAPs must have some
room to receive energy during regenerative braking. When
the car is not moving, UCAPs are fully charged for good
acceleration, with minimum support from the battery.
The simulation in Fig. 11 shows the ZEBRA during regenera-
tive braking from 40 to 0 km/h in 2 s. UCAPs are not connected,
and it can be seen that the battery voltage goes higher than
400 Vdc when the current reaches around
−40
Adc.
However, under real conditions, the control of the inverter
would disrupt the PWM signals to avoid overvoltage condi-
tions. This operation is necessary to avoid a permanent damage
Fig. 6.
Control scheme of the system.
III. C
ONTROL
S
CHEME AND
C
ONTROL
C
IRCUIT
Fig. 6 shows the control circuit in block diagrams, and
Fig. 7 shows the control board implemented for the ZEBRA–
UCAP system. This control scheme was implemented in a
TMS320F241 DSP from Texas Instruments. In addition, a
monitoring feature was implemented in the DSP, which com-
municates with a portable PC. The monitoring program at the
PC allows real-time plotting and storing of all valuable data. In
addition, the control program at the DSP can be commanded
from the PC to work in slave (user-controlled currents) or auto-
mated mode.
The signals required to perform calculations are the follow-
ing: ZEBRA battery voltage, battery current, drive current,
UCAP voltage, input and output currents of the dc–dc con-
verter, UCAP current, battery SOC, and also vehicle speed.
Some of these signals are taken from the main microprocessor
that controls the power inverter. The rest of the signals are
acquired from specially installed sensors and an ampere–hour
counter installed in the vehicle. The control system outputs are
two pulsewidth-modulation (PWM) signals, which commutate
the two insulated-gate bipolar transistors in the buck–boost
dc–dc converter. The PWM is calculated as part of a closed-
loop PI control, comparing a preset current reference and the
measured current from the dc–dc converter. The power transfer
algorithm calculates the preset current value for the current
control, considering the battery SOC, the battery voltage, the
UCAP charge, the vehicle speed, and the power drive system
current.
The transfer algorithm adjusts the amount of energy stored in
the UCAPs according to car speed and battery SOC. The lower
the speed, the higher the UCAP charge. The speed information
is necessary because, at low speeds, more energy is required
for acceleration, and for high speeds, more space for storing
regenerative energy is needed. Similarly, if the batteries are
fully charged, only a small amount of energy stored in the
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946
IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 57, NO. 3, MARCH 2010
Fig. 7. DSP control circuit.
Fig. 11. Regenerative braking simulation from 40 km/h to stop in 2 s, without
UCAPs.
Fig. 8. Transfer algorithm charging curves for UCAP as a function of speed
and battery charge.
Fig. 9. Acceleration simulation from 40 to 60 km/h in 4 s, without UCAPs.
Fig. 12. Regenerative braking simulation from 40 km/h to stop in 2 s, with
UCAPs.
Fig. 10. Acceleration simulation from 40 to 60 km/h in 4 s, with UCAPs.
on the power inverter. The car will be unable to recover an
important part of kinetic energy, and the life of mechanical
brakes will be reduced.
Finally, the simulation in Fig. 12 shows again the ZEBRA
during regenerative braking from 40 to 0 km/h in 2 s. UCAPs
are now connected, and it can be seen that the battery voltage
never goes higher than 400 Vdc because most of the current
is now absorbed by the UCAPs. The UCAP current
I
CAP
is
proportional to
I
COMP
(they are related through the modulation
index of the dc–dc converter). In this case, the regenerative
braking works well because UCAPs take care of the currents,
avoiding battery voltage to go higher than 400 Vdc. It is im-
portant to mention that the control system can be programmed
according to the characteristics of the system. In this case,
two important limits have to be respected: the undervoltage
of 250 Vdc and the overvoltage of 400 Vdc. It is also worth
to mention that regenerative braking with only UCAPs does
not work in large downhills, because they finally will reach
their maximum voltage, being unable to receive more energy.
Under these conditions, the regenerative braking has to be
limited to the capacity of the ZEBRA to receive power without
reaching the voltage limit (400 Vdc). Other solution is to add
power resistors for downhill operation, but this option is very
inefficient because the braking energy is not recovered.
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DIXON
et al.:
ELECTRIC VEHICLE USING A COMBINATION OF ULTRACAPACITORS AND ZEBRA BATTERY
947
Fig. 15. Acceleration tests with UCAPs.
TABLE I
A
CCELERATION
W
ITH AND
W
ITHOUT
UCAP
S
Fig. 13. Urban circuit test course. In red: fast track. In blue: slow track.
Fig. 14. Acceleration tests without UCAPs.
V. E
XPERIMENTAL
R
ESULTS
The following oscillograms and tables show the performance
of the EV with the ZEBRA battery, when it operates with-
out and with the help of UCAPs. All the experiments were
performed with the full equipment installed (UCAPs are dis-
connected electronically). Tests road where made in a circuit
around the university campus, as shown in Fig. 13. The approx-
imate average speed was of 18 km/h, with maximum speeds of
80 km/h in the fast track showed in the external (red) rows.
A. Acceleration Tests
The oscillograms in Figs. 14 and 15 show the acceleration
tests without the UCAP bank and with the UCAP bank, re-
spectively. In Fig. 14, the EV needs around 25 s to reach the
80 km/h at full battery power capability
(P
MAX
= 43
kW).
When
P
MAX
is reached, the battery voltage drops to 250 Vdc.
Under this situation, the control circuit disconnects the power
inverter due to undervoltage protection. However, when the
inverter is disconnected, the ZEBRA voltage goes up, and the
power inverter is connected again. A cyclical off–on operation
is created that can destroy the power inverter (very dangerous
repetitive operation).
When UCAPs are connected, the total power needed by the
power inverter is shared between the ZEBRA (P
MAX
= 29
kW
now) and the UCAPs
(P
MAX
= 45
kW), as shown in Fig. 15.
In this case, the power disruptions are eliminated because the
voltage never drops below 250 V. Moreover, as the traction
power has increased from 43 to 64 kW (29 kW
+
45 kW), the
time to reach 80 km/h has been reduced from almost 25 s to a
little more than 15 s. The total energy delivered by the UCAP is
around 160 Wh, but the stored energy can be restricted to reduce
the size of the UCAPs, because 29 kW delivered by the ZEBRA
is smaller than its
P
MAX
(43 kW). Moreover, if the acceleration
time is increased a little more (20 s), then the necessary energy
stored into the UCAPs will be around 70 Wh. This value is
around 33% of the total energy stored in the actual capacitor
bank (200 Wh). This reduction permits having an UCAP bank
that weighs only 30 kg (frame included) and with a cost of
around US$3000.
The regenerative power is now safer and more efficient be-
cause overvoltages (over 400 Vdc) are avoided with the UCAP
system. During the regenerative braking, the UCAPs recover
part of the kinetic energy. In the cyclic process (stop–start–
stop), some energy is lost and has to be supplied by the battery
to recover the full charge into UCAPs. It is important to say
that the UCAPs do not supply energy during an acceleration–
deceleration cycle (this average energy is zero). They only
flatten the energy delivered by the battery pack.
Table I shows the acceleration time, from zero to different
final speeds (0–40, 0–60, and 0–80 km/h). It can be noticed that
the acceleration time is reduced and UCAP assistance becomes
more significant for higher final speeds.
The information about acceleration shown in Table I was
obtained with the ZEBRA battery almost fully charged (95%
SOC). When the ZEBRA SOC is low, results without UCAPs
become less effective, because battery voltage goes down more
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